Aliphatic hydrocarbons in metasomatized gabbroic xenoliths from Hyblean diatremes (Sicily): Genesis in a serpentinite hydrothermal system     

Enrico Ciliberto  Carmelo Crisafulli  Fabio Carmelo Manuella  Filippo Samperi  Salvatore Scirè  Vittorio Scribano  Marco Viccaro  Ezio Viscuso 《Chemical Geology》2009,258(3-4):258-268

Many tholeiite gabbro xenoliths from the Hyblean tuff-breccia deposits (Sicily, southern Italy) present mineralogical and geochemical evidence for hydrothermal alteration at different temperatures and water/rock ratios. In some cases, the primary mineral assemblage has been entirely replaced by Na-rich alkali feldspar, chlorite/smectite interlayers, zeolites, aegirine–augite, titanite, zircon etc. Hence the chemical composition of such metasomatic rocks displays larger amounts of volatiles, alkalis, Zr, Hf, U, Th and lower Ca, Mg, Fe with respect to the original gabbro. Five hydrothermally altered gabbroic xenoliths were selected for thermal decrepitation and bulk gas analyses by quadrupole mass spectrometry. All the samples analyzed display the same Electron Impact-Direct Pyrolysis Mass spectra (EI-DPMS). These show a series of peaks differing by 14 mass units due to loss of methylene groups (–CH₂), by a fragmentation process typical of saturated aliphatic and aliphatic–aromatic hydrocarbons. In addition, Fourier Transform Infrared (FT-IR) spectra of the samples present several bands typical of vibration frequencies of aliphatic hydrocarbons. The high-molecular-weight hydrocarbons observed probably originated from Fischer–Tropsch-type (FT-t) synthesis in the high temperature section of a serpentinite-hosted hydrothermal system. This suggestion may lend support to the recent hypothesis regarding the original oceanic nature of the Hyblean lithospheric basement.  相似文献   

Estimates of effective permeability for non-Newtonian fluid flow in randomly heterogeneous porous media     

Vittorio Di Federico  Marco Pinelli  Rita Ugarelli 《Stochastic Environmental Research and Risk Assessment (SERRA)》2010,24(7):1067-1076

An understanding of the interplay between non-Newtonian effects in porous media flow and field-scale domain heterogeneity is of great importance in several engineering and geological applications. Here we present a simplified approach to the derivation of an effective permeability for flow of a purely viscous power–law fluid with flow behavior index n in a randomly heterogeneous porous domain subject to a uniform pressure gradient. A standard form of the flow law generalizing the Darcy’s law to non-Newtonian fluids is adopted, with the permeability coefficient being the only source of randomness. The natural logarithm of the permeability is considered a spatially homogeneous and correlated Gaussian random field. Under the ergodic hypothesis, an effective permeability is first derived for two limit 1-D flow geometries: flow parallel to permeability variation (serial-type layers), and flow transverse to permeability variation (parallel-type layers). The effective permeability of a 2-D or 3-D isotropic domain is conjectured to be a power average of 1-D results, generalizing results valid for Newtonian fluids under the validity of Darcy’s law; the conjecture is validated comparing our results with previous literature findings. The conjecture is then extended, allowing the exponents of the power averaging to be functions of the flow behavior index. For Newtonian flow, novel expressions for the effective permeability reduce to those derived in the past. The effective permeability is shown to be a function of flow dimensionality, domain heterogeneity, and flow behavior index. The impact of heterogeneity is significant, especially for shear-thinning fluids with a low flow behavior index, which tend to exhibit channeling behavior.  相似文献   

Dynamics of grains falling on a sloping granular medium: application to the evolution of a talus          下载免费PDF全文

Fabio Vittorio De Blasio  May‐Britt Sæter 《地球表面变化过程与地形》2015,40(5):599-609

Numerous field surveys have provided quantitative information on the characteristics of talus deposits. Much less has been done to quantify the basic dynamics processes of blocks involved in talus evolution. In this work, we perform a set of experiments at the reduced scale of some metres using an inclined board covered with a loose granular medium. The complexity of the processes forming a talus is simplified by studying the interaction of only two kinds of grain sizes at a time. Grains of one class size are dropped from a fixed height onto the board covered by a layer of grains of a different class size, and their final distribution is recorded. We find that when small grains fall on large grains, the granular abundance decreases rapidly as a function of the distance from the fall point, which is explained by the effect of multiple bouncing on the irregular surface. In contrast, large grains falling on a bed of smaller grains lose much more energy at impact. They may stop at once, or roll down slope, often reaching the whole board length; as a consequence, their abundance peaks in the fall zone and at the change of slope. Experiments also show that grains travel longer with increasing fall height and sloping angle. The results clarify in a physical manner one mechanism that might explain why large blocks are typically found in the distal part of a talus slope, while smaller blocks remain near the fall zone. Based on these and previous experiments, a schematic view of talus evolution is discussed. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

Spherical needlets for cosmic microwave background data analysis     

D. Marinucci  D. Pietrobon  A. Balbi  P. Baldi  P. Cabella  G. Kerkyacharian  P. Natoli  D. Picard  N. Vittorio 《Monthly notices of the Royal Astronomical Society》2008,383(2):539-545

We discuss spherical needlets and their properties. Needlets are a form of spherical wavelets which do not rely on any kind of tangent plane approximation and enjoy good localization properties in both pixel and harmonic space; moreover needlet coefficients are asymptotically uncorrelated at any fixed angular distance, which makes their use in statistical procedures very promising. In view of these properties, we believe needlets may turn out to be especially useful in the analysis of cosmic microwave background (CMB) data on the incomplete sky, as well as of other cosmological observations. As a final advantage, we stress that the implementation of needlets is computationally very convenient and may rely completely on standard data analysis packages such as healp ix.  相似文献   

Population II Cepheids in globular clusters     

Filippina Caputo  Vittorio Castellani 《Astrophysics and Space Science》1972,19(2):423-429

B and V data of Population II Cepheids in M2, M5, M10, M13, M80 and ω Cen are combined in order to obtain period-luminosity and period-colour relations. The mean absolute magnitudes are determined adopting as distance modulus the quantily [V(RR)-M _v(RR)], whereV(RR) is the apparent mean magnitude of RR Lyrae andM _v(RR) is the absolute magnitude derived from the transistion periodP _tr. It is shown that the scatter of the points around the (P-L) and (P-C) relations depends also from the width of the instability strip. In fact the position of the variables in the instability strip may be correlated with their amplitude in the sense that the short period variables (logP<1) which have largest amplitudes are brightest and bluest while the long period variables (logP>1) show a reversed relation. Finally, after correcting the observed colours for the amplitude effect, period-colour-amplitude relations are derived for the both short and long period variables.  相似文献   

A search for planets in binary star systems: A new type of approach     

Vittorio Banfi 《Earth, Moon, and Planets》1991,54(3):269-282

A theoretical model, based on particular type of the restricted three-body problem, is here presented in order to demonstrate the existence of a possible planetary motion near the center of mass in a binary star system. The superposition principle is used, with the introduction of two fictitious negative masses in order to simulate the real two primary bodies system.  相似文献   

Impact of the East African Rift System on the routing of the deep-water drainage network offshore Tanzania,western Indian Ocean     

Vittorio Maselli  Dick Kroon  David Iacopini  Bridget S. Wade  Paul N. Pearson  Henk de Haas 《Basin Research》2020,32(5):789-803

The East African Rift System (EARS) exerted a major influence on river drainage basins and regional climate of east Africa during the Cenozoic. Recent studies have highlighted an offshore branch of the EARS in the western Indian Ocean, where the Kerimbas Graben and the Davie Ridge represent its sea floor expression. To date, a clear picture of the impact and timing of this EARS offshore branch on the continental margin of the western Indian Ocean, and associated sediment dispersal pathways, is still missing. This study presents new evidence for four giant canyons along the northern portion of the Davie Ridge offshore Tanzania. Seismic and multibeam bathymetric data highlight that the southernmost three canyons are now inactive, supra-elevated relative to the adjacent sea floor of the Kerimbas Graben and disconnected from the modern slope systems offshore the Rovuma and Rufiji River deltas. Regional correlation of dated seismic horizons, integrated with well data and sediment samples, proves that the tectonic activity driving the uplift of the Davie Ridge in this area has started during the middle-upper Miocene and is still ongoing, as suggested by the presence of fault escarpments at the sea floor and by the location and magnitude of recent earthquakes. Our findings contribute to placing the Kerimbas Graben and the Davie Ridge offshore Tanzania in the regional geodynamic context of the western Indian Ocean and show how the tectonics of the offshore branch of the EARS modified the physiography of the margin, re-routing the deep-water drainage network since the middle Miocene. Future studies are needed to understand the influence of changing sea floor topography on the western Indian Ocean circulation and to evaluate the potential of the EARS offshore tectonics in generating tsunamigenic events.  相似文献   

Landslides in Valles Marineris (Mars): A possible role of basal lubrication by sub-surface ice   总被引：1，自引：0，他引：1  

Fabio Vittorio De Blasio 《Planetary and Space Science》2011,59(13):1384-1392

There is much interest on the occurrence of water and ice in the past history of Mars. Because landslides on Mars are much better conserved than their terrestrial counterparts, a physical examination and morphological analysis can reveal significant details on the depositional environment at the instant of failure. A study of the landslides in Valles Marineris based on their physical aspect is presented and the velocity of the landslides is calculated with a stretching block model. The results show that the landslides were subject to strong basal lubrication that made them travel at high speed and to long distances. We use physical analysis to explore the four alternative possibilities that the natural lubricant of the landslides in Valles Marineris was either ice, deep water, a shallow carpet of water, or evaporites. Examination of the furrows present on the surface of the landslide deposits shows that either sub-surface ice or evaporites were likely present on the floor of Valles Marineris during the mass failures.  相似文献   

Architecture,structural and tectonic significance of the Seagap fault (offshore Tanzania) in the framework of the East African Rift     

David Iacopini  Stefano Tavani  Sara Pentagallo  Vittorio Maselli  Marina Dottore Stagna  Cynthia Ebinger  David Reynolds  Arjan van Vliet 《Basin Research》2023,35(1):387-412

The Southeastern portion of the East African Rift System reactivates Mesozoic transform faults marking the separation of Madagascar from Africa in the Western Indian Ocean. Earlier studies noted the reactivation of the Davie Fracture Zone in oceanic lithosphere as a seismically active extensional fault, and new 3D seismic reflection data and exploration wells provide unprecedented detail on the kinematics of the sub-parallel Seagap fault zone in continental/transitional crust landward of the ocean-continent transition. We reconstruct the evolution of the seismically active Seagap fault zone, a 400-km-long crustal structure affecting the Tanzania margin, from the late Eocene to the present day. The Seagap fault zone is represented by large-scale localized structures affecting the seafloor and displaying growth geometries across most of the Miocene sediments. The continuous tectonic activity evident by our seismic mapping, as well as 2D deep seismic data from literature, suggests that from the Middle-Late Jurassic until 125 Ma, the Seagap fault acted as a regional structure parallel to, and coeval with, the dextral Davie Fracture Zone. The Seagap fault then remained active after the cessation of both seafloor spreading in the Somali basin and strike-slip activity on the Davie Fracture Zone, till nowaday. Its architecture is structurally expressed through the sequence of releasing and restraining bends dating back at least to the early Neogene. Seismic sections and horizon maps indicate that those restraining bends are generated by strike-slip reactivation of Cretaceous structures till the Miocene. Finally based on the interpretation of edge-enhanced reflection seismic surfaces and seafloor data, we shows that, by the late Neogene, the Seagap fault zone switched to normal fault behaviour. We discuss the Seagap fault's geological and kinematic significance through time and its current role within the microplate system in the framework of the East African rift, as well as implications for the evolution and re-activation of structures along sheared margins. The newly integrated datasets reveal the polyphase deformation of this margin, highlighting its complex evolution and the implications for depositional fairways and structural trap and seal changes through time, as well as potential hazards.  相似文献   

Dioxin Like Compounds Bulk Deposition on Corn (Zea mais) and Alfa Alfa (Medicago sativa): Modelled Levels on Derived Silage and Hay and Their Relevance for Dairy Production     

Gianfranco Brambilla  Stefania Paola De Filippis  Vittorio Esposito  Gaetano Settimo 《洁净——土壤、空气、水》2013,41(2):113-118

Dioxin‐like compounds from regular, occasional or fugitive airborne sources of emission may fall out on fodders close to be harvested for silage and hay production. In this way, a prolonged long‐term intake of contaminated forages in dairy animals may be envisaged, able to determine a rise of the background contamination in milk. We simulated different risk scenarios taking into account the inventoried bulk dry depositions in rural areas of the aforesaid contaminants, silage and hay biomass production per hectare, forages regimen in dairy animals, and the congeners carry‐over rate (COR) from forages to milk. Considering atmospheric depositions >10 pg I‐TE m^?2 day^?1 and accounting for a 30% COR, dairy milk could rise up to the PCDD/F level of 3 pg WHO₁₉₉₈‐TE g^?1 fat. The modelling indicates that in rural areas bulk emissions should be selectively minimised, accounting for the calendar of the different agricultural practices, because of their potential impact on the fodders. Since environmental factors play a non‐negligible role in food production, a stronger harmonisation between I‐TE and WHO_1998–2005‐TE scales with respect to dioxin‐like polychlorobiphenyl congeners inclusion is envisaged. This will allow the prevention of the human indirect exposure to such contaminants when released in the air.  相似文献